I also take adderal XR 20mg. If I take it by 7:00 then I take a regular adderal, 10mg at about 5:00. That's only if I have things to do in the evening that require sustained attention, like classes, homework, ect. Some days though, I don't take my XR untill around 11:00 am, so then I don't take anymore that day.
It's hard for me to tell if I've ever overlapped them . It's a pretty low dose, so if it overlapped a little I don't think it would hurt. With meds its all about trials; see what works, doesn't work; try something else. The dosage and timing of the meds have to be taylored specifically to you as an individual.